Metallocene

Titanocene dichloride

FORMURA SUBSTANCETitanocene dichloride
FORMULA[(C5H5)2TiCl2]
CAS No 1271-19-8
APPLICATIONS Catalysts(Polymerization/Hydrogenation/Organic Synthesis),
Electronics Materials, Curing Agent

.pdf Titanocene Dichloride Technical Data

Trial Product Zirconocene dichloride

FORMURA SUBSTANCE Zirconocene dichloride
FORMULA [(C5H5)2ZrCl2]
CAS No 1291-32-3
APPLICATIONS Catalysts(Polymerization/Organic Synthesis),Electronics Materials, Stabilizer

.pdf Zirconocene Dichloride Technical Data

Application to organic syntheses of Zirconocene dichloride

Negishi reagent [Cp2ZrBu2] derived from zirconocene dichloride using was used for high-stereoselective and regioselective coupling reaction or cyclization. For example, multisubstituted pentacene derivatives having high carrier mobility were synthesized by Negishi reagent.

Synthesis of multisubstituted acenes

Takahashi,T.;Kitamura,M.;Shen,B.;Nakajima,K.J.Am.Chem.Soc.2000,122,12876-12877

Trial Product

SUBSTANCE Zirconocene Chloride Hydride(trivial name: Schwartz Reagent)
FORMULA[(C5H5)2ZrHCl]
CAS No 32342-97-5
APPLICATIONSOrganic Synthesis

.pdf Schwartz Reagent Technical Data