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Organometallic Compounds

Technical Information

Nichia supplies high-purity Titanium, Zirconium, Nickel compounds, etc. produced by Nichia's proprietary techniques. These compounds have many applications such as catalysts for polymerization and organic synthesis and raw materials for high performance electronic materials.

Raw Materials
(Metal/Metal Oxide, etc.)
Transition Metal Catalysts/Organometallic Compounds

Organometallic Compound, Metal Carboxylate

Nichia offers a wide range of organic metal complex compounds. Nichia can synthesize organometallic compounds with ligands of cyclopentadiene and its derivatives, alkoxides, phosphines, and organic acid.

Metal Carboxylate
Metal Carboxylate
Metallocene compounds
Metallocene compounds
Nickel Complex
Nickel Complex

M:Metal element R:Alkyl group or hydrogen

Metallocene compounds

Titanocene dichloride

Titanocene dichloride
Substance Titanocene dichloride
Formula [(C5H5)2TiCl2]
CAS No. 1271-19-8
Applications Catalysts (Polymerization/Hydrogenation/Organic Synthesis), Raw Materials for Electronics Materials, Curing Agent

Zirconocene dichloride

Zirconocene dichloride
Substance Zirconocene dichloride
Formula [(C5H5)2ZrCl2]
CAS No. 1291-32-3
Applications Catalysts (Polymerization/Organic Synthesis), Electronics Materials Stabilizer

Application of organic syntheses to Zirconocene dichloride

The Negishi reagent (Cp2ZrBu2), derived from zirconocene dichloride, has been used for high-stereoselective and regioselective coupling reactions or cyclization. For example, polysubstituted pentacene derivatives having high carrier mobility were synthesized by using a Negishi reagent.

Synthesis of polysubstituted acenes

Synthesis of polysubstituted acenes

Trial Product

Trial Product
Substance Zirconocene Chloride Hydride(Schwartz Reagent)
Formula [(C5H5)2ZrHCl]
CAS No. 32342-97-5
Applications Organic Synthesis

Nickel Complex

Trial

Bis (1,5-cyclooctadiene)nickel(0)
Substance Bis(1,5-cyclooctadiene)nickel(0)
Formula [(C8H12)2Ni
CAS No. 1295-35-8
Applications Catalyst / Organic Synthesis

Nickel phosphine complex prototype

Dichlorobis (triphenylphosphine) nickel(Ⅱ)
Substance Dichlorobis (triphenylphosphine) nickel(Ⅱ)
Formula [(C6H5)3P]2NiCl2
CAS No. 14264-16-5
Application Catalyst for cross-coupling of Grignard reagents
1,3-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride
Substance 1,3-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride
Formula {[(C6H5)2P]2(CH2)3}NiCl2
CAS No. 15629-92-2
Application Catalyst for cross-coupling of Grignard reagents
(By using an uncommon ligand, it can also be used for asymmetric Grignard coupling reactions.)
1,2-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride
Substance 1,2-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride
Formula {[(C6H5)2P]2(CH2)2}NiCl2
CAS No. 14647-23-5
Applications Catalyst for cross-coupling of Grignard reagents
(By using an uncommon ligand, it can also be used for asymmetric Grignard coupling reactions.)

Synthesis of prototypes is available upon request.

Metal Carboxylate

Metal Oxide Thin Film

Metal Oxide Thin Film
Example (AFM image)
GO (Gallium Oxide)
20µm、Ra:0.26nm
Other Examples :
ITO (Indium Tin Oxide)
PZT (Titanium Zirconium Lead Oxide)
STO(SrTiO3
Prototype
·Y(CF3COO)3 Yttrium trifluoroacetate
·Ba(CF3COO)2 Barium trifluoroacetate
·Cu(CF3COO)2 Copper trifluoroacetate
(Applications) Superconducting Thin Films

Raw Materials for Metal Oxide Thin Films

*The substances in bold letters in the figure are the substances that can be offered. Contact a Nichia representative to inquire about a prototype synthesis.

Raw Materials for Metal Oxide Thin Films