Organometallic Compounds
Organometallic Compounds
Technical Information
Nichia manufacturers high-purity Gallium, Titanium, Zirconium, Nickel compounds, etc. using Nichia's proprietary techniques. These compounds have many applications such as raw materials for high-performance electronic products, or catalysts for polymerization and organic synthesis.
(Metal/Metal Oxide, etc.)
Organometallic Compound, Metal Carboxylate, Metal-Organic Framework
Nichia offers a wide range of organic metal complex compounds. Nichia can synthesize organometallic compounds with ligands of cyclopentadiene and its derivatives, alkoxides, phosphines, and organic acid.
M:Metal element R:Alkyl group or hydrogen
Gallium Compounds
Nichia offers high-purity gallium compounds manufactured from gallium metal refined in-house. These materials are expected to used in a wide range of applications, particularly in power semiconductor devices. For any questions or inquiries regarding other gallium compounds, contact Nichia.
Trimethylgallium (TMG/TMGa)
| Substance | Trimethylgallium (TMG/TMGa) |
|---|---|
| Formula | Ga(CH3)3 |
| CAS No. | 1445-79-0 |
| Applications | Raw Materials for Electronics Materials |
Triethylgallium (TEG/TEGa)
| Substance | Triethylgallium (TEG/TEGa) |
|---|---|
| Formula | Ga(C2H5)3 |
| CAS No. | 1115-99-7 |
| Applications | Raw Materials for Electronics Materials |
Metallocene Compounds
Titanocene Dichloride
| Substance | Titanocene Dichloride |
|---|---|
| Formula | (C5H5)2TiCl2 |
| CAS No. | 1271-19-8 |
| Applications | Catalysts (Polymerization/Hydrogenation/Organic Synthesis), Raw Materials for Electronics Materials, Curing Agent |
Titanocene Dichloride Technical DataZirconocene Dichloride
| Substance | Zirconocene Dichloride |
|---|---|
| Formula | (C5H5)2ZrCl2 |
| CAS No. | 1291-32-3 |
| Applications | Catalysts (Polymerization/Organic Synthesis), Electronics Materials Stabilizer |
Application of Organic Syntheses to Zirconocene Dichloride
The Negishi reagent (Cp2ZrBu2), derived from zirconocene dichloride, has been used for high-stereoselective and regioselective coupling reactions or cyclization. For example, polysubstituted pentacene derivatives having high carrier mobility were synthesized by using a Negishi reagent.
Synthesis of Polysubstituted Acenes
| Substance | Zirconocene Chloride Hydride（Schwartz Reagent） |
|---|---|
| Formula | (C5H5)2ZrHCl |
| CAS No. | 32342-97-5 |
| Applications | Organic Synthesis |
Nickel Complex
| Substance | Bis(1,5-Cyclooctadiene)Nickel(0) |
|---|---|
| Formula | (C8H12)2Ni |
| CAS No. | 1295-35-8 |
| Applications | Catalyst / Organic Synthesis |
Nickel Phosphine Complex
| Substance | Dichlorobis (Triphenylphosphine) Nickel(Ⅱ) |
|---|---|
| Formula | [(C6H5)3P]2NiCl2 |
| CAS No. | 14264-16-5 |
| Application | Catalyst for cross-coupling of Grignard reagents |
![1,3-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride](../../img/product/catalysts/formula12.png)
| Substance | 1,3-Bis(Diphenylphosphino)ethane] Nickel(Ⅱ) Dichloride |
|---|---|
| Formula | {[(C6H5)2P]2(CH2)3}NiCl2 |
| CAS No. | 15629-92-2 |
| Application | Catalyst for cross-coupling of Grignard reagents (By using an uncommon ligand, it can also be used for asymmetric Grignard coupling reactions.) |
![1,2-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride](../../img/product/catalysts/formula13.png)
| Substance | 1,2-Bis(Diphenylphosphino)ethane] Nickel(Ⅱ) Dichloride |
|---|---|
| Formula | {[(C6H5)2P]2(CH2)2}NiCl2 |
| CAS No. | 14647-23-5 |
| Applications | Catalyst for cross-coupling of Grignard reagents (By using an uncommon ligand, it can also be used for asymmetric Grignard coupling reactions.) |
Synthesis of prototypes is available upon request.
Metal Carboxylate
Metal Oxide Thin Film
GO (Gallium Oxide)
20µm、Ra：0.26nm
ITO (Indium Tin Oxide)
PZT (Titanium Zirconium Lead Oxide)
STO（SrTiO3）
| Y(CF3COO)3 | Yttrium Trifluoroacetate |
|---|---|
| Ba(CF3COO)2 | Barium Trifluoroacetate |
| Cu(CF3COO)2 | Copper Trifluoroacetate |
| (Applications) Superconducting Thin Films | |
Y(CF3COO)3
Ba(CF3COO)2
Cu(CF3COO)2Raw Materials for Metal Oxide Thin Films
*The substances in bold letters in the figure are the substances that can be offered. Contact a Nichia representative to inquire about a prototype synthesis.
Under Development: MOF/PCP
What is MOF/PCP (Metal-Organic Framework/Porous Coordination Polymer)?
MOF/PCP is a new porous material consisting of a regular combination of metal ions and organic compound ligands. In addition to having a vast specific surface area and regular micropores that exceed those of activated carbon and zeolite, MOF/PCP also offers a degree of design freedom which is not found in other materials. It is expected to be used in applications such as gas adsorption, storage, separation, and catalysts.
HKUST-1
| Substance | HKUST-1 |
|---|---|
| Formula | Cu3(C9H3O6)2 |
| CAS No. | 51937-85-0 |
| BET Specific Surface Area | 1,800～1,900 |
| Applications | HKUST-1 is a benchmark compound for micropores. It has excellent gas adsorption properties, including methane adsorption. |
ZIF-8
| Substance | ZIF-8 |
|---|---|
| Formula | Zn(C4H5N2)2 |
| CAS No. | 59061-53-9 |
| BET Specific Surface Area | 1,300～1,500 |
| Applications | ZIF-8 has excellent heat and water resistance, and can be used for propylene/propane separation membranes, etc. |
UiO-66
| Substance | UiO-66 |
|---|---|
| Formula | Zr6(OH)4O4(C8H4O4)6 |
| CAS No. | 1072413-89-8 |
| BET Specific Surface Area | 1,600~1,800 |
| Applications | UiO-66 has excellent chemical and mechanical stability, and is widely used for gas adsorption, catalysts, water purification, etc. |
Nichia can also provide detailed information and consultation on other prototypes.
Contact
For any questions or inquiries regarding Nichia's Organometallic Compounds, use the contact form via the link below.
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